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2019 Vol.24, Issue 1 Preview Page

Article

Background Concentration and Contamination Assessment of Heavy Metals in Korean Coastal Sediments

한반도 연안 퇴적물의 중금속 배경농도 및 오염도 평가

JUNSIK WOO1
,
HYOJIN LEE1
,
JONGKYU PARK1
,
KYOUNGKYU PARK2
,
DONGJIN CHO2
,
DONGJUN JANG2
,
SOJUNG PARK2
,
MANSIK CHOI2*
,
JEONGKYU YOO3
우 준식1
,
이 효진1
,
박 종규1
,
박 경규2
,
조 동진2
,
장 동준2
,
박 소정2
,
최 만식2*
,
유 정규3
1Geosystem Research Corporation, Gunpo
2Department of Marine Environmental Science, Chungnam National University
3Korea Marine Environment Management Corporation
1㈜지오시스템리서치
2충남대학교 해양환경과학과
3해양환경공단
* Corresponding Author
28 February 2019. pp. 64-78
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Abstract

2016~2017년 ‘국가해양생태계 종합조사(연안생태계)’에서 얻어진 495개의 퇴적물 중금속 자료를 이용하여 한반도 연안 퇴적물의 중금속 배경농도를 산정하고 오염도를 평가하였다. 퇴적물 입도를 나타내는 지시자로 Al, Cs, Li이 적절하였으며, 이 들과 중금속 농도 사이의 관계에서 이상치 제거 및 잔차 분석을 통하여 가장 낮은 기울기의 자료를 선택하여 중금속과 지시자 사이의 회귀 직선으로 배경농도를 표시하였다. 기존 연구에서의 배경농도와 본 연구의 결과는 비교적 잘 일치하였으며, 본 연구에서는 As 및 Cd에 대해 처음으로 제시하였고, 지시자로 Li을 사용한 배경농도 식을 처음으로 제시하였다.

The background concentrations of heavy metals in Korean coastal sediments were estimated using heavy metal data for 495 sediments obtained from ‘National Marine Ecosystem Survey (Coastal ecosystem) in 2016-2017’ and the extent of contamination was assessed. Al, Cs, and Li are chosen as appropriate indicators for sediment grain size. In the relationships between heavy metal and indicators concentrations, the lowest slope data were selected through the outlier removal and residual analysis, and the background concentrations were presented as a linear regression line between metal and indicator. Comparing the previous studies for the background concentrations of heavy metals in Korean coastal sediments, concentration levels were generally consistent but those for As and Cd were presented for the first time, and the background concentration using Li as the indicator was presented for the first time.

Keywords
Metals
Korean coastal sediments
Background concentration
Contamination

References
1
Balistrieri, L.S. and T.T. Chao, 1990. Adsorption of selenium by amorphous iron oxyhydroxide and manganese dioxide. Geochimica et Cosmochimica Acta, 54: 739-751.
10.1016/0016-7037(90)90369-V
2
Belzile, N., Y.W. Chen and R. Xu, 2000. Early diagenetic behaviour of selenium in freshwater sediments. Applied Geochemistry, 15: 1439-1454.
10.1016/S0883-2927(00)00011-1
3
Birch, G.F., 2017. Determination of sediment metal background concentrations and enrichment in marine environments – A critical review, Sci of the Total Environment, 580: 813-831.
10.1016/j.scitotenv.2016.12.02827986324
4
Chester, R., 2000. Marine geochemistry. Blackwell Science, Oxford.
5
Cho, D.G., M.S. Choi and C.K. Kim, 2018. Distribution of Total Mercury in Korean Coastal Sediments. J. Korean Soc. Oceanogr, 23: 76-90.
6
Cho, H.C. and Y.G. Cho, 2015. Heavy Metals in Surface Sediments from Doam Bay, Southwestern Coast of Korea. J. Korean Soc. Oceanogr, 20: 159-168.
7
Cho, Y.G. and K.Y. Park 1998. Heavy metals in surface sediments of the Youngsan Estuary, west coast of Korea. J Kor Environ Sci Soc., 7: 549-557.
8
Cho, Y.G., C.B. Lee and M.S. Choi, 1999. Geochemistry of surface sediments off the southern and western coasts of Korea. Mar Geol, 159: 111-129.
10.1016/S0025-3227(98)00194-7
9
Folk, R.L. and W.C. Ward, 1957. Brazos river bar: A study in the significance of grain size parameters. J Sed Petol, 27: 3-26.
10.1306/74D70646-2B21-11D7-8648000102C1865D
10
Förstner, U. and G.T.W. Wittmann, 1981. Metal Pollution in the Aquatic Environment. Springer, Berlin Heidelberg, Berlin, Heidelberg.
10.1007/978-3-642-69385-4
11
Fuküe, M., M. Yanai, Y. Sato, T. Fujikawa, Y. Furukawa, and S. Tani, 2006. Background values for evaluation of heavy metal contamination in sediments. Journal of Hazardous Materials, 136: 111-119.
10.1016/j.jhazmat.2005.11.02016387432
12
Galuszka, A., 2007. A review of geochemical background concepts and an example using data from Poland. Environmental Geology, 52: 861-870.
10.1007/s00254-006-0528-2
13
Horowitz, A.J., 1991. A primer on sediment-trace element chemistry. Lewis Publishers.
10.3133/ofr9176
14
Hwang, D.W., I.S. Lee, M. Choi, S.Y. Kim and H.G. Choi, 2013a. Evaluation of organic matter and trace metal contaminationin surface sediments around the geum River Estuary using sediment quality guidelines. Korean Journal of Fisheries andAquatic Sciences, 46: 930-940.
15
Hwang, D.W., P.J. Kim, R.H. Jung and S.P. Yoon, 2013b. Distributions of organic matter and trace metals in intertidal surface sediment from the Mokpo-Haenam coast. Korean J Fish Aquat Sci., 46: 454-466.
16
Hyun, S.M., T.H. Lee, J.S. Choi, D.L. Choi and H.J. Woo, 2003. Geochemical characteristic sand heavy metal pollutions in the surface sediments of Gwangyang and Yeosu bay, South coast of Korea. J. Korean. Soc. Ocean., 8: 380-391.
17
Jeon, S.G. and Y.G. Cho, 2002. Some heavy metal concentration of surface sediments from the southwestern coast of Korea. J Environ Sci., 11: 1299-1305.
18
Kim, B.S., 2001. Assessment of heavy metal contamination of the coastal surface sediments around Korea. Ph.D.Thesis, Seoul National University, Seoul, 114 pp.
19
Kim, G., H.S. Yang and Y. Kodama, 1998. Distributions of transition elements in the surface sediments of the Yellow Sea. Cont Shelf Res., 18: 1531-1542.
10.1016/S0278-4343(98)00038-7
20
Kim, J.G., S.J. You and W.S. Ahn, 2008. Evaluation of characteristics of particle compostion and pollution of heavy metals for tidal flat sediments in the Julpo Bay, Korea. J Kor Soc Mar Environ Safety, 14: 247-256.
21
Kotze, P., H.H. Preez and J.H.J. van Vuren, 1999. Bioaccumulation of copper and zinc of Oreochromis mossambicus and Clarias gariepinus, from the Olifants river, Mpumalanga, South Afirica. Water SA, 25: 99-110.
22
Lee, M.K., W. Bae, I.K. Um and H.S Jung, 2004. Characteristics of heavy metal distribution in sediments of Youngil Bay, Korea. J Kor Soc Environ Engin, 26: 543-551.
23
Lim, D.I., J.Y. Choi, H.S. Jung, H.W. Choi and Y.O. Kim, 2007. Natural background level analysis of heavy metal concentration in Korean coastal sediments. Ocean and Polar Research, 29: 379-389.
10.4217/OPR.2007.29.4.379
24
Loring, D.H., 1990. Lithium — a new approach for the granulometric normalization oftrace metal data. Marine Chemistry, 29(0): 155-168.
10.1016/0304-4203(90)90011-Z
25
Luoma, S.N., 1990. Processes affecting metal concentrations in estuarine and coastal marine sediments. CRC PRESS, BOCA RATON, FL(USA). 51-66.
26
MacFarlane, G.R. and M.D. Burchett, 2000. Cellular distribution of copper, lead and zinc in the Grey Mangrove Avicennia marina (Forsk.) Vierh. Aquat Bot, 68:45-59.
10.1016/S0304-3770(00)00105-4
27
Martin, J.M. and M. Whitfield, 1983. The significance of river input of chemical elements to the ocean. In: Trace Metals in Sea Water. Wang CS, Boyle E, Burton JD and Goldberg ED, ed. Plenum, New York, U.S.A., 265-298.
10.1007/978-1-4757-6864-0_16
28
Matschullat, J., R. Ottenstein and C. Reimann, 2000. Geochemical background-can we calculate it?, Environ. Geol., 39: 990-1000.
10.1007/s002549900084
29
MOF (Ministry of Oceans and Fisheries), 2013. Korean Standard Method for Marine Environment, MOF Notification. No.2013-230.
30
MOF (Ministry of Oceans and Fisheries), 2016. Protocol of National Survey on Marine Ecosystem, 2nd Edition.
31
MOF (Ministry of Oceans and Fisheries), 2018. Marine Environment guideline, MOF Notification. No.2018-10.
32
Newman, B.K. and R.J. Watling, 2007. Definition of baseline metal concentration for assessing metal enrichment of sediment from the south-eastern.
33
Reimann, C., and R.G. Garrett, 2005. Geochemical background - concept and reality.Science of the Total Environment, 350(1-3): 12-27.
10.1016/j.scitotenv.2005.01.047
34
Rodríguez, J.G., I. Tueros, A. Borja, M.J. Belzunce, J. Franco, O. Solaun, V. Valencia and A. Zuazo, 2006. Maximum likelihood mixture estimation to determine metal background values in estuarine and coastal sediments within the European Water Framework Directive. Science of the Total Environment, 370: 278-293.
10.1016/j.scitotenv.2006.08.035
35
Rubio, B., M.A. Nombela and F. Vilas, 2000. Geochemistry of Major and Trace Elementsin Sediments of the RiadeVigo(NW Spain):an Assessmentof Metal Pollution, Marine Pollution Bulletin, 40: 968-980.
10.1016/S0025-326X(00)00039-4
36
Sahu, K.C. and U. Bhosale, 1991. Heavy metal pollution around the island city of Bombay, India. Part I: quantification of heavy metal pollution of aquatic sediments and recognition of environmental discriminants. Chem Geol, 91: 263-283.
10.1016/0009-2541(91)90104-Y
37
Schropp, S.J., F.G. Lewis, H.L. Windom, J.D. Ryan, F.D. Calder and L.C. Burney, 1990. Interpretation of metalconcentrations in estuarine sediments of Florida using aluminum as a reference element. Estuaries, 13: 227-235.
10.2307/1351913
38
Siegel, F.R., 1995. Environmental geochemistry in development planning: An example from the Nile delta, Egypt. Geochem. Exploration, 55: 265-273.
10.1016/0375-6742(94)00071-9
39
Song, Y. and M.S. Choi, 2017. Assessment of heavy metal contamination in sediments along the coast of South Korea using Cs-normalized background concentrations. Marine Pollution Bulletin, 117: 532-537.
10.1016/j.marpolbul.2017.02.019
40
Song, Y., M.S. Choi, J.Y. Lee and D.J. Jang, 2014. Regional background concentrations of heavy metals (Cr, Co, Ni, Cu, Zn, Pb) in coastal sediments of the South Sea of Korea. Science of the Total Environment, 482: 80-91.
10.1016/j.scitotenv.2014.02.068
41
Summers, J.K., T.L. Wade, V.D. Engle, and Z.A. Malaeb, 1996. Normalization of metal concentration in estuarine sediments from the Gulf of Mexico. Estuaries, 19: 581-594.
10.2307/1352519
42
Taylor, S.R. and S.M., McLennan, 1995. The geochemical evolution of the continental crust. Reviews of Geophys, 33: 241-265.
10.1029/95RG00262
43
Taylor, S.R., 1964. Abundance of chemical elements in the continental crust: A new table. Geochem Cosmochim Acta, 28: 1273-1285.
10.1016/0016-7037(64)90129-2
44
Thornton, I., 1983. Applied environmental geochemistry. Academic Press.
45
Zabetoglou, K., D. Voutsa and C. Samara, 2002. Toxicity and heavy metal contamination of surficial sediments fromBay of Thessaloniki (Northwestern Aegean Sea) Greece. Chemosphere, 49: 17-26.
10.1016/S0045-6535(02)00194-7
46
Zhang, J. and C.L. Liu, 2002. Riverine composition and estuarine geochemistry of particulate metals in China-weathering features, anthropogenic impact and chemical fluxes. Estuar Coast Shelf Sci., 54: 1051-1070.
10.1006/ecss.2001.0879
Information
  • Publisher :The Korean Society of Oceanography
  • Publisher(Ko) :한국해양학회
  • Journal Title :The Sea Journal of the Korean Society of Oceanography
  • Journal Title(Ko) :한국해양학회지 바다
  • Volume : 24
  • No :1
  • Pages :64-78
  • Received Date : 2019-01-08
  • Revised Date : 2019-01-28
  • Accepted Date : 2019-01-30
  • DOI :https://doi.org/10.7850/jkso.2019.24.1.064
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